Two-dimensional surface phase diagram of a multicomponent perovskite oxide: <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mrow><mml:msub><mml:mi>La</mml:mi><mml:mrow><mml:mn>0.8</mml:mn></mml:mrow></mml:msub><mml:msub><mml:mi>Sr</mml:mi><mml:mrow><mml:mn>0.2</mml:mn></mml:mrow></mml:msub><mml:msub><mml:mi>MnO</mml:mi><mml:mn>3</mml:mn></mml:msub><mml:mrow><mml:mo>(</mml:mo><mml:mn>110</mml:mn><mml:mo>)</mml:mo></mml:mrow></mml:mrow></mml:math>
نویسندگان
چکیده
The many surface reconstructions of (110)-oriented lanthanum--strontium manganite (La$_{0.8}$Sr$_{0.2}$MnO$_3$, LSMO) were followed as a function the oxygen chemical potential ($\mu_\text{O}$) and cation composition. Decreasing $\mu_\text{O}$ causes Mn to migrate across surface, enforcing phase separation into A-site-rich areas variety composition-related, structurally diverse B-site-rich reconstructions. composition these phase-separated structures was quantified with scanning tunneling microscopy (STM), results used build 2D diagram LSMO(110) equilibrium structures.
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ژورنال
عنوان ژورنال: Physical Review Materials
سال: 2021
ISSN: ['2476-0455', '2475-9953']
DOI: https://doi.org/10.1103/physrevmaterials.5.l092401